The link is to www.libreoffice.org
It is in the beta, perhaps it will be created as site-name.
Reproducible with LibreOffice 3.3.0 - WIN XP FR [OOO330m9 (Build:1 - build 184.108.40.206)]: Info Button links to <http://www.documentfoundation.org/fr>, but that web page does not exist.
Steps to reproduce:
1. Start localized version of Libre Office without
selected application, so that Start Center appears
2. Click info button
expected: localized Web Page
actual: Error 404
No problem with EN version, links to
So it seems that the problem only exists for non English Languages.
This very visible problem is a blocker for 3.3.0. Currently link should lead to general English web site, where links to local pages can be listed.
What localization / language did you test?
Should be working now. Made some server-side rewrite tricks.
Yes, I checked with DE and FR and some fantasy localizations (xy/, ab/), it seems that the trick works for all 2 letter subfolders.